BEGIN:VCALENDAR
VERSION:2.0
PRODID:-//132.216.98.100//NONSGML kigkonsult.se iCalcreator 2.20.4//
BEGIN:VEVENT
UID:20250811T183349EDT-5820DXBj8U@132.216.98.100
DTSTAMP:20250811T223349Z
DESCRIPTION:The interplay of redox-active transition metal ions and pro-rad
 ical ligands in metalloenzyme sites has generated considerable interest. T
 he Cu(II)-phenoxyl radical form of galactose oxidase\, as well as the Fe(I
 V)=O porphyrin radical intermediate of P450 enzymes are principal examples
 . Both of these enzymatic systems have inspired efforts to develop small m
 olecule mimics capable of mild and selective oxidation chemistry. Recent d
 evelopments show that ligands serving as electron reservoirs offer opportu
 nities to expand catalysis\, especially by conferring to first-row transit
 ion metals a “noble metal-like” reactivity.[1] We have extensively investi
 gated the chemistry of a series of oxidized mono- and bis-phenoxide metal 
 complexes\, which demonstrate that small variations of the ligand structur
 e affect the oxidation locus. Characterization of oxidized species by both
  experimental and theoretical methods has afforded significant information
  about the electronic structure of these ligand radical systems. Building 
 on this work\, recent studies with a series of oxidized nitridomanganese(V
 ) salen complexes demonstrate that nitride activation is dictated by remot
 e ligand electronics.[2] We are currently investigating the reaction mecha
 nism and further applications of this chemistry. \n\n1.       P. J. Chirik
  and K. Wieghardt\, Science\, 2010\, 327\, 794.\n\n2.       R. M. Clarke a
 nd T. Storr\, J. Am. Chem. Soc. 2016\, 138\, 15299\n
DTSTART:20171024T170000Z
DTEND:20171024T183000Z
LOCATION:OM 10\, Maass Chemistry Building\, CA\, QC\, Montreal\, H3A 0B8\, 
 801 rue Sherbrooke Ouest
SUMMARY:Chemical Society Seminar: Dr. Tim Storr - Electronic Structure and 
 Reactivity of Oxidized Metal Phenoxides 
URL:/chemistry/channels/event/chemical-society-seminar
 -dr-tim-storr-electronic-structure-and-reactivity-oxidized-metal-phenoxide
 s-278792
END:VEVENT
END:VCALENDAR